Diazidobis[2,4-diamino-6-(2-pyridyl)-1,3,5-triazine-kappa N-2(1),N-6]zinc(II)

作者:Zhao Qi Hua; Fan Ai Ling; Li Li Nan; Xie Ming Jing
来源:Acta Crystallographica Section E-Structure Reports Online, 2009, 65(6): M622-U269.
DOI:10.1107/S1600536809016055

摘要

In the title mononuclear complex, [Zn(N-3)(2)(C8H8N6)(2)], the Zn-II atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral environment by four N atoms from two 2,4-diamino-6-(2-pyridyl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H center dot center dot center dot N hydrogen bonds between the ligand and azide ion link the complex molecules into a three-dimensional network.