摘要

Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound cr...