An effective strategy to tune supramolecular interaction via a spiro-bridged spacer in oligothiophene-S,S-dioxides and their anomalous photoluminescent behavior

作者：Xie, Ling-Hai^*; Hou, Xiao-Ya; Hua, Yu-Ran; Huang, Yan-Qin; Zhao, Bao-Min; Liu, Feng; Peng, Bo; Wei, Wei; Huang, Wei

来源：Organic Letters, 2007, 9(9): 1619-1622.

DOI：10.1021/ol070006u

• RIGID-CORE OLIGOTHIOPHENE-S,S-DIOXIDES
• SOLID-STATE
• FLUORESCENT MARKERS
• OLIGOMERS
• ISOTHIOCYANATES
• EFFICIENCIES
• CRYSTAL

We demonstrate that incorporating nonplanar spiro-bridged structures is an effective strategy for tuning supramolecular interactions of optoelectronic functional moieties. In the model compounds spiro-bridged oligothiophene-S,S-dioxides (BSiSDTFO), unusual dimers constructed by spiro-bridged spacers do not form excimers, which is confirmed by crystallographic data and fluorescent emission spectra.

• 出版日期2007-4-26
• 单位南京邮电大学; 复旦大学