Dipole induced anomalous S-shape I-V curves in polymer solar cells

作者:Kumar Ankit*; Sista Srinivas; Yang Yang
来源:Journal of Applied Physics, 2009, 105(9): 094512.
DOI:10.1063/1.3117513

摘要

A kink is sometimes seen in the I-V curves for organic solar cells. In literature charge blocking has been speculated to be responsible for such kind of anomalous features. In this manuscript, we use poly (3-hexylthiophene):[6, 6]-phenyl-C(61)-butyric acid methyl ester as our model polymer system and investigate different device structures using ultraviolet photoelectron spectroscopy as our primary tool to investigate the reason for this S-shaped kink. We attribute this anomalous feature to the presence of strong interface dipoles. We further propose a model based on the standard set of Poisson equation, continuity equation, and current density equations including both drift and diffusion components.

  • 出版日期2009-5-1

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