Arene-ligated heteroleptic terphenolate complexes of thorium

作者:McKinven Jamie; Nichol Gary S; Arnold Polly L*
来源:Dalton Transactions, 2014, 43(46): 17416-17421.
DOI:10.1039/c4dt02995j

摘要

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-eta(6)-arene interactions in a thorium bis(arene) sandwich motif.

  • 出版日期2014