A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst

作者：Sutradhar Manas; Kirillova Marina V; Guedes da Silva M Fatima C; Martins Luisa M D R S; Pombeiro Armando J L^*

来源：Inorganic Chemistry, 2012, 51(21): 11229-11231.

DOI：10.1021/ic3017062

The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions.

• 出版日期2012-11-5