Methylene crosslinked calix[6]arene hexacaarboxylic acid resin: A highly efficient solid phase extractant for decontamination of lead bearing effluents

作者：Adhikari Birendra Babu; Gurung Manju; Kawakita Hidetaka; Jumina; Ohto Keisuke^*

来源：Journal of Hazardous Materials, 2011, 193: 200-208.

DOI：10.1016/j.jhazmat.2011.07.051

• Calixarenes
• Solid-phase extraction
• Lead
• Column separation
• Elution

Calixarene-based cation exchange resin has been developed by methylene crosslinking of calix[6]arene hexacarboxylic acid derivative and the resin has been exploited for solid phase extraction of some toxic heavy metal ions. The selectivity order of the resin towards some metal ions follows the order Pb(II) > Cu(II) > Zn(II), Ni(II), Co(II). The maximum lead ion binding capacity of the resin was found to be 1.30 mmol g(-1) resin. The loaded lead was quantitatively eluted with dilute acid solution regenerating the resin. Mutual separation of Pb(II), Cu(II) and Zn(II) was achieved by using the column packed with the resin.

• 出版日期2011-10-15