Mixed valence mono- and hetero-metallic grid catenanes

作者:Giri Chandan; Topic Filip; Cametti Massimo; Rissanen Kari
来源:Chemical Science, 2015, 6(10): 5712-5718.
DOI:10.1039/c5sc01851j

摘要

Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono-and hetero-metallic [2]-catenanes made of [2 x 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(II)/Cu(I) pair and of the conformationally adaptable organic ligands for achieving catenation of grids.

  • 出版日期2015