An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

作者:Doherty Simon*; Knight Julian G; Ellison Jack R; Weekes David; Harrington Ross W; Hardacre Christopher; Manyar Haresh
来源:Green Chemistry, 2012, 14(4): 925-929.
DOI:10.1039/c2gc16679h

摘要

A linear cation-decorated polymeric support with tuneable surface properties and microstructure has been prepared by ring-opening metathesis polymerisation (ROMP) of a pyrrolidinium-functionalised norbornene-based monomer with cyclooctene. The derived peroxophosphotungstate-based polymer-immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.

  • 出版日期2012