A lvt-type framework material [Pb3Cl3(OH)(succinate)](n) with helical sub-structures and incomplete cubane-like clusters

作者：Zhang, Haixia; Kang, Yao; Tan, Yanxi; Wang, Fei^*

来源：Inorganic Chemistry Communications, 2011, 14(1): 197-199.

DOI：10.1016/j.inoche.2010.10.021

• Hydrothermal synthesis
• Lead
• Topology
• Helix
• Incomplete cubane-like cluster

Presented here are the hydrothermal synthesis, single crystal XRD characterization and physical property of a polymeric lead(II) compound, (Pb3Cl3(OH)(succinate)(n) (1). In the structure of 1, the succinate ligands bridge the trinuclear incomplete cubane-like Pb3O3Cl clusters to form a non-interpenetrating three-dimensional framework with lvt (4(2)8(4)) topology. Single helices with the same ratio of different orientation are found in this unusual network.

• 出版日期2011-1
• 单位中国科学院福建物质结构研究所; 结构化学国家重点实验室