科研之友
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摘要
Through extensive molecular modelling of Fe-III/IV-oxo and Fe-III-hydroxo complexes it is shown here unambiguously that the assignment of the iron oxidation state of a Sc3+-capped iron-oxygen species should be revised. Iron in this Lewis-acid capped metal-bound oxygen system is Fe-III, coinciding with water as a secondary axial ligand to scandium.
- 出版日期2013
