Preparation, characterization and electrical conductivity studies of nanocrystalline La doped BaMoO4

作者：Nallamuthu N; Prakash I; Satyanarayana N^*; Venkateswarlu M

来源：Materials Research Bulletin, 2011, 46(1): 32-41.

DOI：10.1016/j.materresbull.2010.10.001

• Nanostructures
• Sol-gel chemistry
• X-ray diffraction
• Infrared spectroscopy
• Impedance spectroscopy

Different compositions of scheelite type nanocrystalline La doped BaMoO4 [Ba1-xLaxMoO4+x/2, where x = 0, 0.1, 0.2, 0.3, 0.4 and 0.5] samples were prepared by acrylamide assisted sol-gel combustion process. Dried gels prepared at 60 degrees C were heated at different temperatures and characterized using TG/DTA, XRD, FTIR and SEM-EDX techniques. From XRD patterns, crystalline phases for La-doped BaMoO4 samples were confirmed and their average crystallite sizes were calculated using Scherrer's formula and it was found to be less than 80 nm. Structure and thermal behavior of scheelite type nanocrystalline La doped BaMoO4 samples were identified respectively using FTIR and TG/DTA measurements. Microstructure and existence of O, La, Ba and Mo elements in the La doped BaMoO4 samples were obtained from SEM-EDX and HRTEMtechniques. The 'd' spacing values were obtained for different (h k l) planes and were well matched with the standard BaMoO4, (h k l) values for different directions of planes were assigned for the observed HRTEM images and were matched with standard BaMoO4. Grain and grain boundary conductivities were evaluated by analyzing the impedance data, using the Winfit software, measured at different temperatures.

• 出版日期2011-1