科研之友
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摘要
A series of rigid Pt(II) diimine diacetylide complexes and their corresponding metallocyclic derivatives were synthesized through coordination-driven self-assembly. The photophysical properties of these complexes have been studied in detail, revealing exceptionally high RT phosphorescence quantum yields and lifetimes when the excited state becomes localized on the pi-conjugated bridging-ligand following intramolecular charge-transfer sensitization.
- 出版日期2011
