Dehydrogenative coupling of silanes with alcohols catalyzed by Cu-3(BTC)(2)

作者：Dhakshinamoorthy Amarajothi; Concepcion Patricia; Garcia Hermenegildo

来源：Chemical communications, 2016, 52(13): 2725-2728.

DOI：10.1039/c5cc10216b

Cu-3(BTC)(2) is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(II) and in situ generated Cu(I) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling.

• 出版日期2016