Computationally Efficient Pseudo-2D Non-Isothermal Modeling of Polymer Electrolyte Membrane Fuel Cells with Two-Phase Phenomena

作者：Goshta**i Alireza; Pence Benjamin L; Ersal Tulga

来源：Journal of the Electrochemical Society, 2016, 163(13): F1412-F1432.

DOI：10.1149/2.0871613jes

In this article, a computationally efficient pseudo-2D model for real-time dynamic simulations of polymer electrolyte membrane fuel cells (PEMFCs) is developed with a specific focus on water and thermal management. The model accounts for temperature dynamics, two-phase flow and flooding in the diffusion media, and membrane water crossover as well as absorption and desorption processes. Computational efficiency is achieved by leveraging the disparate time scales within the system dynamics, in addition to exploiting the large aspect ratio of the cell layers to create a spatio-temporal decoupling. Taking advantage of such decoupling, the model yields a computationally efficient solution while providing detailed information about the state of water and temperature throughout the cell. Through this approach, the current implementation of the model is found to be about twice faster than real time. Moreover, a case study is carried out where different mechanisms contributing to overall water balance in the cell are investigated. The results are shown to be in qualitative agreement with published experimental data, thereby providing a preliminary validation of the modeling approach. Finally, using the modeling results, an equivalent electrical circuit model is proposed to help elucidate water transport inside various cell layers.

• 出版日期2016