Mechanism of the Far-Infrared Absorption of Carbon-Nanotube Films

作者:Kampfrath T*; von Volkmann K; Aguirre C M; Desjardins P; Martel R; Krenz M; Frischkorn C; Wolf M; Perfetti L
来源:Physical Review Letters, 2008, 101(26): 267403.
DOI:10.1103/PhysRevLett.101.267403

摘要

The far-infrared conductivity of single-wall carbon-nanotube ensembles is dominated by a broad absorption peak around 4 THz whose origin is still debated. We observe an overall depletion of this peak when the nanotubes are excited by a short visible laser pulse. This finding excludes optical absorption due to a particle-plasmon resonance and instead shows that interband transitions in tubes with an energy gap of similar to 10 meV dominate the far-infrared conductivity. A simple model based on an ensemble of two-level systems naturally explains the weak temperature dependence of the far-infrared conductivity by the tube-to-tube variation of the chemical potential.

  • 出版日期2008-12-31