Monitoring structural transformations in crystals. 13. On photocyclization in 2,3,4,5,6-pentamethylbenzophenone, 1,3-diphenylbutan-1-one and 2,4,6-triisopropyl-4 '-methoxybenzophenone

作者：Bakowicz Julia; Turowska Tyrk Ilona^*

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2010, 66(1): O29-O32.

DOI：10.1107/S0108270109052858

The geometrical parameters governing the potential for the photocyclization reaction occurring in crystals of 2,3,4,5,6-pentamethylbenzophenone, C(18)H(20)O, (I), 1,3-diphenylbutan-1-one, C(16)H(16)O, (II), and 2,4,6-triisopropyl-40-methoxybenzophenone, C(23)H(30)O(2), (IV), have been evaluated. Compound (IV) undergoes photocyclization but (I) and (II) do not, despite the fact that their geometrical parameters appear equally favourable for reaction. The structure of the partially reacted crystal of the photoactive compound, i.e. 2,4,6-triisopropyl-40-methoxybenzophenone-3,5-diisopropyl-7-(4-methoxyphenyl)-8,8-dimethylbicyclo[4.2.0]octa-1,3,5-trien-7-ol (9/1), 0.90C(23)H(30)O(2)center dot 0.10C(23)H(30)O(2), (III), was also determined, providing structural evidence for the reactivity of the compound. It has been found that the carbonyl group of the photoactive compound reacts with one of the two o-isopropyl groups. The study has shown that the intramolecular geometrical parameters are not the only factors influencing the reactivity of compounds in crystals.

• 出版日期2010-1