Nb-Doped TiO2 Nanofibers for Lithium Ion Batteries

作者:Fehse M*; Cavaliere S; Lippens P E; Savych I; Iadecola A; Monconduit L; Jones D J; Roziere J; Fischer F; Tessier C; Stievanot L
来源:Journal of Physical Chemistry C, 2013, 117(27): 13827-13835.
DOI:10.1021/jp402498p

摘要

Niobium-doped nanofibers elaborated by facile, single-step electrospinning present a higher rate capability in electrochemical cycling experiments than nondoped materials. This is attributed to the reduction of Li+ diffusion path lengths and enhanced intimate interparticle contact, in combination with improved intraparticle conductivity. Niobium doping has a significant effect on the electronic structure and provokes a substantial decrease in particle size.

  • 出版日期2013-7-11