Low-temperature biaxial nematic from rod and disc mesogen mixture

作者:Berardi Roberto*; Zannoni Claudio
来源:Soft Matter, 2012, 8(6): 2017-2025.
DOI:10.1039/c1sm06838e

摘要

Molecular dynamics computer simulations have been employed to demonstrate that the addition of a suitable uniaxial discotic nematic to a biaxial nematic (N(b)) of elongated mesogens can give rise to a low temperature N(b) liquid crystal (where the rod-like particles would form a biaxial smectic). The two species are made to be fully miscible over the entire isotropic and nematic temperature range by a suitable parameterisation of shapes and pair interactions. The disc-like mesogen, even though not forming a biaxial nematic by itself gives a stable low-temperature discotic nematic which strongly disfavours the formation of columnar and smectic phases in the two-component system.

  • 出版日期2012