A water pipe held up by a polyoxometalate supported transition metal complex: Synthesis and characterization of [Cu-2(phen)(2)(CH3COO)(CH3COOH)(H2O)(2)][Al(OH)(6)Mo6O18]center dot 28H(2)O

作者：Shivaiah Vaddypally; Chatterjee Tanmay; Srinivasu Khandregula; Das Samar K^*

来源：European Journal of Inorganic Chemistry, 2007, (2): 231-234.

DOI：10.1002/ejic.200600751

• heteropolyanion
• copper acetate dimer
• crystal structure
• lattice waters
• hydrogen bonds
• supramolecular chemistry

A water pipe, formed exclusively from lattice water molecules, is stabilized in an organic-inorganic hybrid material Cu-2(phen)(2)(CH3COO) (CH3COOH) (H2O)(2)] [Al(OH)(6)Mo6O18]center dot 28H(2)O (1). Compound 1 consists of an Anderson-type heteropolyanion, a copper acetate dimer, and 28 lattice water molecules. Once the relevant crystal is removed from the mother liquor it loses water molecules, which results in the demolition of the water pipe.

• 出版日期2007-1