A three-dimensional metal-organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour

Mahata Partha; Sen Diptiman<sup>*</sup>; Natarajan Srinivasan

doi:10.1039/b715314g

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A three-dimensional metal-organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour

作者：Mahata Partha; Sen Diptiman^*; Natarajan Srinivasan

来源：Chemical Communications, 2008, (11): 1278-1280.

DOI：10.1039/b715314g

摘要

Three-dimensional [Mn(3){C(6)H(3)(COO)(3))(2)] comprising two-dimensional -Mn-O-Mn- distorted Kagome layers, formed by two geometrically different hexa-coordinated Mn(2+) ions, show less frustration and spin canted long range ordering possibly due to antisymmetric exchange.