A carbon-free polyoxometalate molecular catalyst with a cobalt-arsenic core for visible light-driven water oxidation

作者：Chen, Wei-Chao; Wang, Xin-Long^*; Qin, Chao; Shao, Kui-Zhan; Su, Zhong-Min^*; Wang, En-Bo

来源：Chemical communications, 2016, 52(61): 9514-9517.

DOI：10.1039/c6cc03763a

• CLUSTERS

A carbon-free, stable, homogeneous water oxidation catalyst based on the unique hepta-nuclear cobalt-arsenic core ("fused" double-quasi-cubane) and polyoxometalate ligands, Na-12[{(Co7As6O9)-As-II-O-III(OH)(6)}-(A-alpha-SiW9O34)(2)]center dot 8H(2)O (1), was synthesized, thoroughly characterized and employed to catalyze water oxidation under visible-light-driven conditions.

• 出版日期2016
• 单位东北师范大学