摘要
Polarized second-order Raman scattering spectra of CuO single crystals are reported. It is shown that for some scattering geometries the second-order processes dominate the inelastic light scattering spectra. Group-theoretical symmetry analysis of the selection rules for the first-and second-order scattering processes is performed and phonon dispersion relations are calculated within density functional theory. The main spectral features of the two-phonon spectra are assigned to overtones of the vibrational branches at various special points across the Brillouin zone.
- 出版日期2013-3-13