摘要
A microporous Zn-based anionic metal-organic framework (MOF) was synthesized with triangular 4,4',4 ''-(pyridine-2,4,6-triyl)tribenzoic acid. The anionic MOF material featuring open channels proved to be a good capturing agent for the cationic dye methylene blue. In addition, the Zn-MOF demonstrated excellent catalytic activity for CO2 fixation by cycloaddition reaction with epoxides for the generation of cyclic carbonates.
- 出版日期2016-9