An experimental and theoretical study of the polar [2+3] cycloaddition reactions between 1-chloro-1-nitroethene and (Z)-C-aryl-N-phenylnitrones

作者：Jasinski Radomir^*; Mikulska Maria; Baranski Andrzej

来源：CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2013, 11(9): 1471-1480.

DOI：10.2478/s11532-013-0276-6

• [2+3] cycloaddition
• Nitrone
• Kinetic study
• DFT calculations
• Global nucleophilicity

Kinetic studies and B3LYP/6-31g(d) calculations indicate the polar nature of [2+3] cycloadditions between 1-chloro-1-nitroethene to (Z)-C-aryl-N-phenylnitrones. This is clearly confirmed by the activation parameters and the substituent and solvent effects.

• 出版日期2013-9