Double-emission-layer green phosphorescent OLED based on LiF-doped TPBi as electron transport layer for improving efficiency and operational lifetime

作者：Yang Qian; Hao Yuying^*; Wang Zhenguo; Li Yunfei; Wang Hua; Xu Bingshe

来源：Synthetic Metals, 2012, 162(3-4): 398-401.

DOI：10.1016/j.synthmet.2011.12.027

• Phosphorescent OLED
• Double emission layers
• Doped charge transport layers
• High efficiency
• Long lifetime

We demonstrate an excellent electrophosphorescent organic light-emitting diodes (PHOLEDs) with double-emitting layers (D-EML) and LiF-doped TPBi as electron transport layer (ETL), which has the structure of ITO/NPB (30 nm)/CBP:Ir(ppy)(3) (20 nm)/TPBi:Ir(ppy)(3) (10 nm)/TPBi (10 nm)/TPBi:LiF (40 nm)/LiF (1.2 nm)/Al (150 nm). A peak current efficiency of 40.5 cd/A and a maximum power efficiency of 23.7 lm/W have been achieved, 1.99 and 2.95 times of those of the reference device IITO/NPB (30 nm)/CBP:Ir(ppy)3 (30 nm)/TPBi (10 nm)/Alq(3) (40 nm)/LiF (1.2 nm)/Al (150 nm)], respectively. And the device shows better stability than reference device at high current density. Moreover, the operational lifetime is improved, nearly 35 times of that of the reference device. We attribute mainly these improvement to the carriers' self-balancing character of D-EML OLEDs, less numbers of heterojunction interface and better electron transport property of TPBi:LiF.

• 出版日期2012-3
• 单位太原理工大学