科研之友
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摘要
In the presence of p-toluenesulfonic acid, the reaction of alkenes with diselenides and oxidant m-chloroperbenzoic acid proceeds efficiently in alcohols at room temperature, and was developed into a convenient procedure for the alkoxylselenenylation of alkenes, forming a series of corresponding 2-alkoxy-1-selenenyl compounds with high regioselectivity and good yields. The reaction conditions are optimized and a plausible mechanism for the acid promotion is suggested.
- 出版日期2015
- 单位浙江工业大学
