A reversible two-electron redox system involving a divalent lead species

作者:Saito Masaichi*; Nakada Marisa; Kuwabara Takuya; Minoura Mao
来源:Chemical communications, 2015, 51(22): 4674-4676.
DOI:10.1039/c4cc09856k

摘要

Reduction of THF-stabilized plumbacyclopentadienylidene with lithium afforded dilithioplumbole. On the other hand, oxidation of the dilithioplumbole provided the starting plumbacyclopentadienylidene. This is the unprecedented example of a reversible interconversion between group 14 M(II) and its dianionic species bearing organic substituents.

  • 出版日期2015