Abnormal synergistic effects between Lewis acid- base interaction and halogen bond in F3B center dot center dot center dot NCX center dot center dot center dot NCM

作者：Tang, Qingjie; Li, Qingzhong^*

来源：Molecular Physics, 2015, 113(23): 3809-3814.

DOI：10.1080/00268976.2015.1065352

• synergistic effect
• covalent interaction
• halogen bond

An abnormal synergistic effect was found between the Lewis acid-base interaction and halogen bond in triads F3B???NCX???NCM (X and M are halogen atoms), where the strong Lewis acid-base interaction between F3B and NCX has a larger enhancement than the weak halogen bond between NCX and NCM. This is in contrast with the traditional cooperative effect. It is interesting that the alkali-metal substituent as well as the heavier halogen atom play a more remarkable role in the enhancement of the interaction F3B???NCX than that of NCX???NCM, particularly, the alkali-metal substituent makes the abnormal synergistic effect be the traditional cooperative one.

• 出版日期2015-12-2
• 单位河南理工大学; 烟台大学