摘要

The bee's nest-like nanostructured CeO2-Al2O3 powders were synthesized by combustion method using polyvinyl alcohol as a fuel and their catalytic activity were tested in the m-xylene and toluene combustion. The results showed that the catalytic reaction temperature increased monotonically from 200 to 250 degrees C and from 250 to 300 degrees C for the 90% conversion of m-xylene and toluene, respectively, with the calcination temperature in the range of 450-850 degrees C. For both combustions, the sample calcined at 450 degrees C with a bee's nest-like nanostructure and average pore size of 800 nm exhibited the highest catalytic activity. Among the samples calcined at 850 degrees C, the lowest catalytic reaction temperature for the 90% conversion of m-xylene and toluene of 250 and 300 degrees C, respectively, was found with the sample having the equimolar ratio of Ce/Al.

  • 出版日期2013-6

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