Bipyridyltriazolium Chlorobismuthate with Thermo-/Photochromic and Photoluminescent Switching Behaviors Based on ET and CT

作者：Li, Guoping; Hao, Pengfei; Shen, Junju; Yu, Tanlai; Li, Huihui; Fu, Yunlong^*

来源：Inorganic Chemistry, 2016, 55(21): 11342-11347.

DOI：10.1021/acs.inorgchem.6b01906

• METAL-ORGANIC FRAMEWORK
• ELECTRON-TRANSFER
• CHARGE-TRANSFER
• COORDINATION POLYMERS
• PI INTERACTIONS
• VIOLOGEN
• CRYSTALS
• SYSTEM
• SEPARATION
• COMPLEXES

Matched with 3,5-bis(pyridine-2-yl)-1,2,4-triazole (2-bpt), a new electron donor-acceptor-based chlorobismuthate(III) hybrid, [2-bpt](2)[Bi2Cl10(H2O)]center dot 5H(2)O was prepared solvo-thermally and characterized. The title compound (hydrated form) and its dehydrated form exhibit photo- and thermo-induced intermolecular electron transfer (ET), which correspond to dual ET photo/thermochromism for hydrated form, charge transfer thermochromism during dehydration, and simultaneously photo luminescent responses, respectively.

• 出版日期2016-11-7
• 单位山西师范大学