Systems modeling, simulation and material operating requirements for chemical hydride based hydrogen storage

作者：Devarakonda Maruthi^*; Brooks Kriston; Roennebro Ewa; Rassat Scot

来源：International Journal of Hydrogen Energy, 2012, 37(3): 2779-2793.

DOI：10.1016/j.ijhydene.2011.06.121

• Hydrogen storage
• Chemical hydride
• Ammonia borane
• Systems modeling and simulation
• Material operating requirements
• On-board efficiency

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydride based hydrogen storage. AB was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to similar to 16% by weight for the release of similar to 2.5 M equivalents of hydrogen gas) and its stability under typical ambient conditions. Another promising candidate is alane, AlH3 (10.1% by weight). Materials operating requirements to use chemical hydrides for vehicle onboard storage are discussed. A flow-through system concept based on augers, ballast tank, hydrogen heat exchanger and H-2 burner was designed and implemented in simulation. In this design, the chemical hydride material was assumed to produce H-2 in the auger itself, thus minimizing the size of ballast tank and reactor. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure, in various components of the storage system. Various subsystem components in the models were coded as 'C' language S-functions and implemented in Matlab/Simulink. Steady state simulation results for all the three candidate materials (solid AB, liquid AB and alane) were presented to show the proof of concept, whereas the drive cycle simulations were discussed only for solid AB using the fuel cell H-2 demand for four different US drive cycles. Conditional logic based controllers that control the material flow rate into the reactor and to control the H-2 fed to the burner were developed and implemented in drive cycle simulations. Simulation results show that the proposed system meets most of the 2010 DOE targets, and is well above the required > 40% of the DOE targets for fill time, well-to-powerplant efficiency, and volumetric and gravimetric density.

• 出版日期2012-2