A Multifunction Pd/Sc(OTf)(3)/Ionic Liquid Catalyst System for the Tandem One-Pot Conversion of Phenol to epsilon-Caprolactam

作者：Shin Ju Yeon; Jung Da Jung; Lee Sang gi^*

来源：ACS Catalysis, 2013, 3(4): 525-528.

DOI：10.1021/cs400009w

• multifunction catalyst
• tandem catalysis
• hydrogenation
• phenol
• caprolactam

A multifunction Pd/Sc(OTf)(3)/ionic liquid catalyst for the tandem one-pot conversion of phenol to e-caprolactam is reported. Pd and Sc(OTf)(3) cooperate to catalyze the hydrogenation of phenol to cyclohexanone with excellent conversion (%26gt;99.9%) and selectivity (%26gt;99.9%), whereas Sc(OTf)(3) and an ionic liquid, [bmim] [PF6], cooperate to catalyze the tandem transformation of the resulting cyclohexanone to cyclohexanone oxime and the Beckmann rearrangement affording epsilon-caprolactam.

• 出版日期2013-4