Dual Self-Healing Abilities of Composite Gels Consisting of Polymer-Brush-Afforded Particles and an Azobenzene-Doped Liquid Crystal

作者：Kawata Yuki; Yamamoto Takahiro^*; Kihara Hideyuki; Ohno Kohji

来源：ACS Applied Materials & Interfaces, 2015, 7(7): 4185-4191.

DOI：10.1021/am5084573

• liquid crystal
• gel
• azobenzene
• self-healing
• phase separation

We prepared the composite gels from polymer-brush-afforded silica particles (P-SiPs) and an azobenzene-doped liquid crystal, and investigated their inner structure, dynamic viscoelastic properties, thermo- and photoresponsive properties, and self-healing behaviors. It was found that the composite gels had a sponge-like inner structure formed with P-SiPs and exhibited good elastic property and shape recoverability. The surface dents made on the composite gel could be repaired spontaneously at room temperature. Moreover, the composite gel exhibited a gel-sol transition induced by the trans-cis photoisomerization of the azo dye, and the transition could be used as a mending mechanism for surface cracks. Consequently, we successfully developed a material exhibiting two types of self-healing abilities simultaneously: (1) spontaneous repair of surface dents by means of the excellent elasticity of the composite gel and (2) light-assisted mending of surface cracks by photoinduced gel-sol transition.

• 出版日期2015-2-25