Dual reactivity of 1-chloro- and 1-bromo-3,5-dinitrobenzenes in aromatic nucleophilic substitution

作者：Dutov Mikhail D^*; Shevelev Svyatoslav A; Koshelev Vladimir N; Aleksanyan David R; Serushkina Olga V; Neverova Olga D; Kolvina Evgeniya V; Bobrov Egor S

来源：Mendeleev Communications, 2017, 27(2): 160-162.

DOI：10.1016/j.mencom.2017.03.018

Aromatic nucleophilic substitution reactions in 1-halo-3,5-dinitrobenzenes (where the halogen is bromine or chlorine) can occur with replacement of either a nitro group or a halogen atom, depending on the nature of anionic nucleophile Nu(-) as a Lewis base (hard, soft or intermediate), as well as on the polarity of the dipolar aprotic solvent.

• 出版日期2017-4
• 单位北京化工大学