An analysis of non-equilibrium peritectic reaction driven by solute diffusion under a temperature gradient

作者:Liu, Dongmei; Li, Xinzhong; Su, Yanqing*; Luo, Liangshun; Zhang, Bo; Chen, Ruirun; Guo, Jingjie; Fu, Hengzhi
来源:Journal of Crystal Growth, 2011, 334(1): 195-199.
DOI:10.1016/j.jcrysgro.2011.08.034

摘要

Experiments consisting of melting followed by thermal stabilization under a temperature gradient have been performed on Al-Ni peritectic alloys. A non-planar interface around the peritectic temperature has been observed. This is found to be induced by the primary Al3Ni2 phase dissolution above the equilibrium peritectic temperature T-P. A solute depleted zone in a distance above T-P and a solute enriched zone below T-P have been characterized. The dissolution perturbation is explained in light of the constitutional superheating driven by solute diffusion under a temperature gradient.

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