A hybrid organic-inorganic molecular daisy chain

作者:Fernandez Antonio; Pineda Eufemio Moreno; Ferrando Soria Jesus; McInnes Eric J L; Timco Grigore A; Winpenny Richard E P*
来源:Chemical Communications, 2015, 51(55): 11126-11129.
DOI:10.1039/c5cc02216a

摘要

A hybrid organic-inorganic molecular daisy chain has been synthesised in one pot reaction. The molecule contains two {Cr6Zn2} rings linked through an organic molecule that acts as both template and ligand. Magnetic and spectroscopic data reveal themagnetic complexity of the daisy chain, which can be casted to two magnetic isomers through comparison of experimental and simulated data for Cr(III) chains.

  • 出版日期2015