A composite material with Ce-O2-ZrO2 nanocrystallines embedded in SiO2 matrices and its enhanced thermal stability and oxygen storage capacity

作者：Yang, Runnong; Liu, Yumei; Yu, Lin^*; Zhao, Xiangyun^*; Yang, Xiaobo; Sun, Ming; Luo, Junyin; Fan, Qun; Xiao, Jianming; Zhao, Yuzhong

来源：Journal of Nanoparticle Research, 2018, 20(6): 151.

DOI：10.1007/s11051-018-4255-x

• Ceria-zirconia nanocrystallites
• Silica matrices
• Thermal stability
• Oxygen storage capacity
• Three-way catalyst

A simple hydrothermal procedure is introduced, which leads to the successful synthesis of a new composite material with fine CeO2-ZrO2 nanocrystallites embedded in amorphous and porous SiO2 matrices. The composite material possesses an extraordinary high thermal stability. After being calcined at 1000 \s=deg\C, it retains CeO2-ZrO2 nanocrystallites of the size around 5 nm, a BET-specific surface area of 165 m(2)/g, and an oxygen storage capacity of 468 \g=m\mol/g. No phase segregation for CeO2-ZrO2 nanocrystallites is detected and the SiO2 matrices remain not crystallized. The composite material shows a great potential as a support of three-way catalyst, as evidenced in catalytic tests with supported Pt.

• 出版日期2018-6-1
• 单位广东工业大学