科研之友
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摘要
Density functional theory (DFT) calculations of nitrogen-directed intramolecular electrophilic borylation reaction of arenes, which is widely used for construction of functional molecules, indicate that the reaction proceeds through an intramolecular Friedel Crafts route, rather than through C-H insertion, and the reactivity difference between BCl3 and BBr3 is due to the higher electronegativity of Cl.
- 出版日期2015-10-5
- 单位RIKEN
