Rhenium complexes of peripherally pi-extended N-confused porphyrins

作者:Yamamoto Takaaki; Toganoh Motoki; Mori Shigeki; Uno Hidemitsu; Furuta Hiroyuki*
来源:Chemical Science, 2012, 3(11): 3241-3248.
DOI:10.1039/c2sc20708g

摘要

Peripherally pi-extended N-confused porphyrin rhenium complexes were synthesized by the rhenium-mediated reactions of N-confused porphyrins with 2-methyl azaarene and the structures were elucidated by X-ray crystallographic analyses. Extension of the pi-conjugation in the complexes was supported by the absorption spectra, electrochemical measurements and theoretical calculations.

  • 出版日期2012-11