A three-dimensional open framework constructed by rod SBUs and T-shaped linkers

作者：Chen, Shu-Mei^*; Lian, Ting-Ting

来源：Inorganic Chemistry Communications, 2010, 13(12): 1380-1382.

DOI：10.1016/j.inoche.2010.07.040

• Metal-organic framework
• 3,3 ' 4,4 '-benzophenone-tetracarboxylate
• Hydrothermal synthesis
• Porous material

A metal-coordination polymer [Co(4)(BPTC)(2)(H(2)O)(8)]center dot 13H(2)O (1, BPTC = 3,3'4,4'-benzophenone-tetracarboxylate) containing nano-sized channels was hydrothermally synthesized. It has remarkable 3D architecture generated by unique rod-shaped SBUs(SBUs = Secondary Building Units) linked up by T-shaped ligands and present a novel constructional strategy of 3D porous metal-organic framework. One-dimensional water pipes are formed in the channels, which further stabilize the 3D framework.

• 出版日期2010-12
• 单位福州大学