科研之友
微信
新浪微博
Facebook
分享链接
摘要
squaraine-based system was developed and demonstrated to fluorescently and colorimetrically sense CO2 gas with high sensitivity in DMSO in the presence of fluoride ion. From results, large hypsochromic shifts were observed both in the absorption spectra (134 nm) and fluorescence spectra (126 nm), and the color change of solution could be clearly observed by the naked eye in response to carbon dioxide gas. Combining H-1 NMR titration tests and theoretical calculations, a plausible sensing mechanism that the deprotonated SQ-NH2 with fluoride ion will rapidly restore on condition that acidic carbon dioxide gas bubbles in DMSO is proposed and further revealed. Moreover, theoretical studies agree with experimental data well.
