摘要

The correlations between kinetic parameters and both operational conditions and process performance during the anaerobic digestion of food waste were investigated. Substrate concentration (SC), biomass concentration (BC), and substrate-inoculum ratio (S/I) were selected as the operational conditions, while first-order and modified Gompertz models were introduced to evaluate digestion kinetics. The results indicated that no significant correlations between both hydrolysis and methanogenesis kinetic parameters (k and R-m) relative to the operational conditions and process parameters could be determined; however, k/R'(m) was observed to significantly correlate with these parameters. Specifically, substrate load (both SC and S/I) positively influenced k/R'(m) via its impact on volatile fatty acid (VFA) and pH, while BC reduced k/R'(m) by increasing the alkalinity of the system. Moreover, k/R'(m) was negatively correlated with process efficiency. The methane recovery rate exceeded 90% when 1.55 <k/R'(m) <3.13, but decreased by 50% when k/R'(m) >4.64 (p = 0.05). These findings provide a scientific foundation for predicting the behavior of anaerobic systems and optimizing the digestion process.