Nitrile-Rich Coordination Polymer (1)(infinity){[Fe(CH3CN)(4)(pyrazine)](CIO4)(2)} Exhibiting a HS reversible arrow LS Transition

作者：Bialonska Agata; Bronisz Robert^*; Darowska Kamilla; Drabent Krzysztof; Kusz Joachim; Siczek Milosz; Weselski Marek; Zubko Maciej; Ozarowski Andrew

来源：Inorganic Chemistry, 2010, 49(24): 11267-11269.

DOI：10.1021/ic102040y

In a 1D network of (1)(infinity){[Fe(CH3CN)(4)(pyrazine)}(CIO4)(2)], the presence of four neutral nitrile molecules besides the pyrazine donors in the first coordination sphere of iron(II) allows one to achieve a ligand field strength appropriate for the "spin-crossover" occurrence.

• 出版日期2010-12-20