Molecular structures of thimerosal (Merthiolate) and other arylthiolate mercury alkyl compounds

作者：Melnick Jonathan G; Yurkerwich Kevin; Buccella Daniela; Sattler Wesley; Parkin Gerard^*

来源：Inorganic Chemistry, 2008, 47(14): 6421-6426.

DOI：10.1021/ic8005426

The molecular structure of sodium ethylmercury thiosalicylate (also known as thimerosal and Merthiolate) and related arylthiolate mercury alkyl compounds, namely PhSHgMe and PhSHgEt, have been determined by single crystal X-ray diffraction. H-1 NMR spectroscopic studies indicate that the appearance of the Hg-119 mercury satellites of the ethyl group of thimerosal is highly dependent on the magnetic field and the viscosity of the solvent as a consequence of relaxation due to chemical shift anisotropy.

• 出版日期2008-7-21