The first electro-induced asymmetric Stevens rearrangement of (S)- and (R)-N-benzyl proline-derived ammonium salts

作者：Palombi Laura^*

来源：Catalysis Communications, 2011, 12(6): 485-488.

DOI：10.1016/j.catcom.2010.10.027

• Electrocatalysis
• Stevens rearrangement
• Chiral ammonium salts

The Stevens rearrangement of N-benzyl proline derivatives ammonium ylides can be readily accomplished by galvanostatic electrolysis of the corresponding ammonium salts in the cathode compartment of a divided-cell. With respect to the well-established chemical methods, the electro-induced process showed a significant amplification of the nitrogen to carbon chirality transmission.

• 出版日期2011-2-10