Macrocyclic hexanuclear zirconium(IV) complex bearing a bisaryloxyl N-heterocyclic-carbene ligand: Synthesis, structure, and catalytic properties

作者：Zhang Dao^*; GengShi Gongwo; Wang Jinyang; Yue Qin; Zheng Wenjun; Weng Linhong

来源：Inorganic Chemistry Communications, 2010, 13(3): 433-435.

DOI：10.1016/j.inoche.2010.01.005

• Zirconium
• N-heterocyclic carbene ligands
• Aryloxyl
• Multinuclear complex
• Ethylene polymerization

A rare macrocyclic hexazirconium(IV) complex with bisaryloxyl N-heterocyclic carbene ligand {(L)Zr(OSiMe(3))(k(2)-[N(boolean AND)O])}(6) (2) (L = 1 3-[3, 5-Bu(2)(t)-2-O(-)-(C(6)H(2))CH(2)](2)(C(3)H(2)N(2)).H[N(boolean AND)O]=1-[3 5-Bu(2)(1)-2-OH-(C(6)H(2))CH(2))](C(3)H(3)N(2))) Was prepared from a mononuclear complex [(L)ZrCl(

• 出版日期2010-3
• 单位复旦大学