Nano-iron oxide-catalyzed selective oxidations of alcohols and olefins with hydrogen peroxide

作者：Shi Feng; Tse Man Kin; Pohl Marga Matina; Radnik Joerg; Brueckner Angelika; Zhang Shengmao; Beller Matthias^*

来源：Journal of Molecular Catalysis A: Chemical , 2008, 292(1-2): 28-35.

DOI：10.1016/j.molcata.2008.06.008

• Nano-catalysts
• Iron oxide
• Oxidation
• Green chemistry
• Hydrogen peroxide
• Alcohols

Unsupported "free" nano-gamma-Fe(2)O(3) is an active, stable, and reusable catalyst for selective oxidations of alcohols and olefins applying hydrogen peroxide as terminal oxidant. Catalyst activity and selectivity are controlled by tuning the particle size. The formation of a thin carbon-layer on the surface of the nano-iron oxide during the reaction permits for high catalyst stability. All catalysts were characterized by TEM, X-ray photoelectron spectroscopy (XPS), XRD, and EPR.

• 出版日期2008-9-17
• 单位河南大学