Aerosol Jet Printed, Low Voltage, Electrolyte Gated Carbon Nanotube Ring Oscillators with Sub-5 mu s Stage Delays

作者:Ha Mingjing; Seo Jung Woo T; Prabhumirashi Pradyumna L; Zhang Wei; Geier Michael L; Renn Michael J; Kim Chris H; Hersam Mark C; Fri**ie C Daniel*
来源:Nano Letters, 2013, 13(3): 954-960.
DOI:10.1021/nl3038773

摘要

A central challenge for printed electronics is to achieve high operating frequencies (short transistor switching times) at low supply biases compatible with thin film batteries. In this report, we demonstrate partially printed five-stage ring oscillators with >20 kHz operating frequencies and stage delays <5 mu s at supply voltages below 3 V. The fastest ring oscillator achieved 1.2 mu s delay time at 2 V supply. The inverter stages in these ring oscillators were based on ambipolar thin film transistors (TFTs) employing semiconducting, single-walled carbon nanotube (CNT) networks and a high capacitance (similar to 1 mu F/cm(2)) ion gel electrolyte as the gate dielectric. All materials except the source and drain electrodes were aerosol jet printed. The TFTs exhibited high electron and hole mobilities (similar to 20 cm(2)/(V s)) and ON/OFF current ratios (up to 10(5)). Inverter switching times t were systematically characterized as a function of transistor channel length and ionic conductivity of the gel dielectric, demonstrating that both the semiconductor and the ion gel play a role in switching speed. Quantitative scaling analysis suggests that with suitable optimization low voltage, printed ion gel gated CNT inverters could operate at frequencies on the order of 1 MHz.