Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid-solid interface

作者：Elemans Johannes A A W^*; Wezenberg Sander J; Coenen Michiel J J; Escudero Adan Eduardo C; Benet Buchholz Jordi; den Boer Duncan; Speller Sylvia; Kleij Arjan W; De Feyter Steven

来源：Chemical Communications, 2010, 46(15): 2548-2550.

DOI：10.1039/b922212j

Nickel salophens exclusively form monolayers at a liquid-solid interface, while in contrast zinc salophens mainly self-assemble into bilayers via axial ligand self-coordination which can be disrupted by the addition of pyridine axial ligands.

• 出版日期2010